The Perfect Boy and Without You are up on iTunes (US).
Some store reports:
"The single (both 7'' and CD) is out today in Ireland @ HMV" (Thanks Vikk)
"My local FYE store (Tacoma, WA) had four copies of The Perfect Boy when I dropped in during my lunch break." (Thanks Brad)
"I got the CD today from HMV on Market Street in Manchester." (Thanks John)